Bis(4-methyl-3,5-diphenyl-1H-pyrazole-κN2)silver(I) nitrate

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Bis(4-methyl-3,5-diphenyl-1H-pyrazole-κN 2)silver(I) nitrate

In the title complex, [Ag(C(16)H(14)N(2))(2)]NO(3), the geometry around the Ag(I) ion is T-shaped with two short Ag-N bonds to the pyrazole ligand and one long Ag-O bond to the nitrate anion. The crystal structure is stabilized by inter-molecular N-H⋯O, C-H⋯O and C-H⋯π inter-actions.

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3-Methyl-1,5-diphenyl-4,5-dihydro-1H-pyrazole

In the title compound, C16H16N2, the dihydro-pyrazole ring adopts a shallow envelope conformation, with the C atom bearing the phenyl group displaced by 0.298 (2) Å from the other atoms (r.m.s. deviation = 0.015 Å). The dihedral angles between the four near coplanar atoms of the central ring and the N- and C-bonded phenyl groups are 13.49 (13) and 82.22 (16)°, respectively.

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N′-Benzoyl-5-methyl-1,3-diphenyl-1H-pyrazole-4-carbohydrazide

In the title compound, C24H20N4O2, the pyrazole ring makes dihedral angles of 47.57 (10)° and 30.56 (11)° with its N-bound and C-bound phenyl groups, respectively. The C-N-N-C group that links the two carbonyls has a torsion angle of 81.5 (2)°. The torsion angles between the carbonyl groups and their adjacent pyrazole and phenyl rings are 125.89 (19) and 164.22 (17)°, respectively. In the cryst...

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Ethyl 1,5-diphenyl-1H-pyrazole-4-carboxyl­ate

The asymmetric unit of the title compound, C(18)H(16)N(2)O(2), contains two independent mol-ecules (A and B). In mol-ecule A, the pyrazole ring is inclined at angles of 48.86 (6) and 60.80 (6)° with respect to the two phenyl rings; the corresponding angles for mol-ecule B are 46.86 (6) and 58.63 (6)°. In the crystal, mol-ecules of type A are linked into sheets parallel to (001) via weak C-H⋯O h...

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1,3-Diphenyl-1H-pyrazole-4-carbaldehyde

There are four mol-ecules in the asymmetric unit of the title compound, C(16)H(12)N(2)O. The dihedral angle between the phenyl rings in the mol-ecules are 22.2 (2), 22.4 (2), 25.1 (3) and 41.9 (2)°. In the crystal, mol-ecules form dimers due to inter-molecular C-H⋯O hydrogen bonds, which result in one R(2) (2)(10) and two R(2) (1)(7) ring motifs. Weak aromatic π-π stacking [centroid-centroid se...

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2011

ISSN: 1600-5368

DOI: 10.1107/s1600536811017776